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掺混CeO2纳米粒子对生物柴油液滴蒸发特性的影响

Effect of Doped CeO2 Nanoparticles on Evaporation Characteristics of BioDiesel Droplets

  • 摘要:
    目的 为了探索发动机的清洁能源,需要对燃料的蒸发特性进行研究。
    方法 在棕榈酸甲酯(MP)和油酸甲酯(MO)中添加不同浓度的CeO2纳米粒子制备了纳米流体燃油,通过单液滴蒸发实验研究了773 K和973 K下掺混CeO2(质量分数为0~500×10−6)对MP和MO混合液滴蒸发特性的影响。
    结果 结果表明:在773 K下,MP20MO80和MP20MO80+50CeO2液滴的蒸发以波动蒸发阶段为主,但是随着CeO2浓度进一步增大,混合液滴的蒸发阶段逐渐向稳态蒸发阶段转变,在973 K下液滴蒸发过程以波动蒸发阶段为主;在773 K下添加CeO2纳米粒子的生物柴油液滴的瞬态蒸发阶段时间占比小于未添加纳米粒子的液滴,973 K下液滴的波动蒸发阶段时间占比相较于773 K有大幅提高;在773 K和973 K下,液滴的蒸发速率均随着CeO2浓度的增大呈现出先增大后减小的趋势,当CeO2质量分数为50×10−6时,液滴的蒸发速率达到最大,分别为0.125 mm2/s和0.373 mm2/s;973 K下液滴的蒸发速率高于773 K下液滴的蒸发速率,这是因为温度升高促进了液滴各组分的蒸发和微爆炸的发生。
    结论 研究结果可为CeO2纳米粒子在发动机燃料中的实际应用提供价值参考。

     

    Abstract:
    Objective In order to explore clean energy sources for engines, the evaporation characteristics of fuels need to be investigated.
    Method Nanofluidic fuels were prepared by adding CeO2 nanoparticles with different concentrations to methyl palmitate (MP) and methyl oleate (MO), and the effects of CeO2 doping (mass fraction of 0~500×10−6) on the evaporation characteristics of the MP and MO blended droplets were investigated by single-droplet evaporation experiments at 773 and 973 K. The results were summarized as follows.
    Result The results show that at 773 K, the evaporation of MP20MO80 and MP20MO80+50CeO2 droplets is dominated by fluctuating evaporation stage, but with the further increase of CeO2 concentration, the evaporation stage of mixed droplets gradually changes to steady evaporation stage, and the evaporation process of droplets is dominated by fluctuating evaporation stage at 973 K; At 773 K, the proportion of transient evaporation phase time of biodiesel droplets with CeO2 nanoparticles is less than that of droplets without nanoparticles, and the proportion of fluctuating evaporation phase time of droplets at 973 K is greatly improved compared with that at 773 K; At 773 K and 973 K, the evaporation rate of droplets increases first and then decreases with the increase of CeO2 concentration. When the mass fraction of CeO2 is 50×10−6, the evaporation rate of droplets reaches the maximum, which is 0.125 mm2/s and 0.373 mm2/s respectively. The evaporation rate of droplets at 973 K is higher than that at 773 K, because the temperature increase promotes the evaporation of droplets and the occurrence of micro-explosion.
    Conclusion The results of the study can provide valuable references for the practical application of CeO2 nanoparticles in engine fuels.

     

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