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Haizhou LIN, Zhibin LUO, Aiguo PEI, Hui YANG, Xiaobo WANG. Technology and Industrialization Progress on Methanol Synthesis from Carbon Dioxide and Hydrogen[J]. SOUTHERN ENERGY CONSTRUCTION, 2020, 7(2): 14-19. DOI: 10.16516/j.gedi.issn2095-8676.2020.02.002
Citation: Haizhou LIN, Zhibin LUO, Aiguo PEI, Hui YANG, Xiaobo WANG. Technology and Industrialization Progress on Methanol Synthesis from Carbon Dioxide and Hydrogen[J]. SOUTHERN ENERGY CONSTRUCTION, 2020, 7(2): 14-19. DOI: 10.16516/j.gedi.issn2095-8676.2020.02.002
shu

Technology and Industrialization Progress on Methanol Synthesis from Carbon Dioxide and Hydrogen

  • China Energy Engineering Group Guangdong Electric Power Design Institute Co., Ltd., Guangzhou 510663, China

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  • Received Date: May 09, 2020
  • Revised Date: May 19, 2020
    Abstract
  • Introduction Carbon dioxide hydrogenation to methanol is one of the important pathways to realize the large-scale utilization of carbon dioxide and it will favor the development of CCUS industrial chain.
      Method  Thermodynamic characteristics, catalyst development, industrialization progress and technical economics of carbon dioxide hydrogenation to methanol were reviewed.
      Result  Cu-based catalysts, precious metal catalysts and In2O3 catalyst shows good catalytic performance in carbon dioxide hydrogenation to methanol, but they still need to be further improved to increase the carbon dioxide conversion rate and methanol selectivity. Despite the rapid progress in technology of carbon dioxide hydrogenation to methanol, which is currently in the pilot stage, it is presently difficult to apply on a large scale due to high cost of hydrogen and low price of methanol.
      Conclusion  Fortunately, the price of hydrogen will drop with the booming of the hydrogen industry, and the national carbon trading market will also start, which are beneficial to the blossom of carbon dioxide hydrogenation to methanol.
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  • LIN Haizhou,LUO Zhibin,PEI Aiguo,et al.Technology and Industrialization Progress on Methanol Synthesis from Carbon Dioxide and Hydrogen[J].Southern Energy Construction,2020,07(02):14-19.

    • References (32)
  • [1]
    IPCC. Climate change 2014: synthesis report [R]. Geneva, Switzerland: IPCC, 2014.
    [2]
    NationsUnited. United Nations framework convention on climate change [R]. Rio de Janeiro, Brazil: United Nations, 2015.
    [3]
    BP. Statistical review of world energy [R]. London: BP, 2019.
    [4]
    林海周, 杨晖, 罗海中, 等. 烟气二氧化碳捕集胺类吸收剂研究进展 [J]. 南方能源建设, 2019, 6(1): 16-21.

    LINH Z, YANGH, LUOH Z, et al. Research progress on amine absorbent for CO2 capture from flue gas [J]. Southern Energy Construction, 2019, 6(1): 8-14.
    [5]
    林海周, 裴爱国, 方梦祥. 燃煤电厂烟气二氧化碳胺法捕集工艺改进研究进展 [J]. 化工进展, 2018, 37(12): 4874-4886.

    LINH Z, PEIA G, FANGM X. Progress of research on process modifications for amine solvent-based post combustion CO2 capture from coal-fired power plant [J]. Chemical Industry and Engineering Progress, 2018, 37(12): 4874-4886.
    [6]
    SHIC F, ZHANGT, LIJ, et al. Powering the future with liquid sunshine [J]. Joule, 2018, 2(10): 1925-1949.
    [7]
    JIANGX, NIEX, GUOX, et al. Recent advances in carbon dioxide hydrogenation to methanol via heterogeneous catalysis [J]. Chemical Reviews, 2020, online. doi: 10.1021/acs.chemrev.9b00723.
    [8]
    AHMADK, UPADHYAYULAS. Greenhouse gas CO2 hydrogenation to fuels: a thermodynamic analysis [J]. Environmental Progress & Sustainable Energy, 2019, 38(1): 98-111.
    [9]
    侯瑞君, 邱瑞, 孙克宁. Cu基CO2合成甲醇催化剂载体的研究进展 [J]. 化工进展, 2020, online. doi: 10.16085/j.issn.1000-6613.2019-1546.

    HOUR J, QIUR, SUNK N. Progress in the Cu-based catalyst supports for methanol synthesis from CO2 [J]. Chemical Industry and Engineering Progress, 2020, online. doi: 10.16085/j.issn.1000-6613.2019-1546.
    [10]
    WANGW, QUZ, SONGL, et al. CO2 hydrogenation to methanol over Cu/CeO2 and Cu/ZrO2 catalysts: tuning methanol selectivity via metal-support interaction [J]. Journal of Energy Chemistry, 2020, 40(1):22-30.
    [11]
    WANGZ Q, XUZ N, PENGS Y, et al. High-performance and long-lived Cu/SiO2 nanocatalyst for CO2 hydrogenation [J]. ACS Catalysis, 2015, 5(7): 4255-4259.
    [12]
    闫晓峰, 高文桂, 毛文硕, 等. 溶胶-凝胶法制备Cu-ZnO-ZrO2催化剂：柠檬酸用量对催化剂性能的影响 [J]. 化工进展, 2020, online. doi: 10.16085/j.issn.1000-6613.2019-2051.

    YANX F, GAOW G, MAOW S, et al. Preparation of Cu-ZnO-ZrO2 catalyst by sol-gel method: effect of citric acid content on catalyst performance [J]. Chemical Industry and Engineering Progress, 2020, online. doi: 10.16085/j.issn.1000-6613.2019-2051.
    [13]
    LAM E, LARMIERK, TADAS, et al. Zr(IV) surface sites determine CH3OH formation rate on Cu/ZrO2/SiO2 - CO2 hydrogenation catalysts [J]. Chinese Journal of Catalysis, 2019, 40(11): 1741-1748.
    [14]
    林敏, 纳薇, 叶海船, 等. 不同助剂对CuO-ZnO/SBA-15催化CO2加氢制甲醇性能影响的研究 [J]. 燃料化学学报, 2019, 47(10): 1214-1225.

    LINM, NAW, YEH C, et al. Effect of additive on CuO-ZnO/SBA-15 catalytic performance of CO2 hydrogenation to methanol [J]. Journal of Fuel Chemistry and Technology, 2019, 47(10): 1214-1225.
    [15]
    FUJITANIT, SAITOM, KANAIY, et al. Development of an active Ga2O3 supported palladium catalyst for the synthesis of methanol from carbon dioxide and hydrogen [J]. Applied Catalysis A: General, 1995, 125(2): 199-202.
    [16]
    LINF, JIANGX, BORERIBOONN, et al. Effects of supports on bimetallic Pd-Cu catalysts for CO2 hydrogenation to methanol [J]. Applied Catalysis A: General, 2019(585): 117210.
    [17]
    HARTADIY, WIDMANND, BEHMR J. CO2 Hydrogenation to methanol on supported Au catalysts under moderate reaction conditions: support and particle size effects [J]. Chem SusChem, 2015, 8(3): 456-65.
    [18]
    SUNK H , FANZ G, YEJ Y, et al. Hydrogenation of CO2 to methanol over In2O3 catalyst [J]. Journal of CO2 Utilization, 2015, 12（1）: 1-6.
    [19]
    曹晨熙, 陈天元, 丁晓旭, 等. 负载型铟基催化剂二氧化碳加氢动力学研究 [J]. 化工学报, 2019, 70(10): 3985-3993.

    CAOC X, CHENT Y, DINGX X, et al. Kinetics study on supported indium-based catalysts in carbon dioxide hydrogenation [J]. CIESC Journal, 2019, 70(10): 3985-3993.
    [20]
    MARTINO, MARTN A J, MONDELLIC, et al. Indium oxide as a superior catalyst for methanol synthesis by CO2 hydrogenation [J]. Angewandte Chemie International Edition, 2016, 55(21): 6261-6265.
    [21]
    吴晓辉. Pd/In2O3/SBA-15催化CO2加氢合成甲醇及其性能研究 [D]. 天津：天津大学, 2018.

    WUX H. Study of CO2 hydrogenation to methanol over Pd/In2O3/SBA-15 catalyst [D]. Tianjin: Tianjin University, 2018.
    [22]
    史建公, 刘志坚, 刘春生. 二氧化碳加氢制备甲醇技术进展 [J]. 中外能源, 2018, 23(9): 56-70.

    SHIJ G, LIUZ J, LIUC S. Advances in technologies for CO2 hydrogenation to methanol [J]. Sino-global Energy, 2018, 23(9): 56-70.
    [23]
    IEA. Putting CO2 to use creating value from emissions[R]. Paris: IEA, 2019.
    [24]
    Carbon Capture Journal. Mitsubishi selected to conductresearch on effective recycling of CO2 to produce methanol. [EB/OL] (2020-04-06) [2020-05-17] http://www.carboncapturejournal.com/ViewNews.aspx?NewsID=4326.
    [25]
    中国科学院. 中科院完成二氧化碳加氢制甲醇工业单管实验 [J]. 乙醛醋酸化工, 2016(7): 48.

    Chinese Academy of Sciences. The Chinese Academy of Sciences completed the industrial single-tube experiment of the carbon dioxide hydrogenation to methanol [J]. Acetaldehyde Acetic Acid Chemical, 2016(7): 48.
    [26]
    中国科学院. 中科院二氧化碳甲醇技术完成工艺包编制 [J]. 天然气化工(C1化学与化工), 2016, 41(3): 15.

    Chinese Academy of Sciences. The Chinese Academy of Sciences completed preparation of process package of CO2 to methanol technology [J]. Natural Gas Chemical Industry, 2016, 41(3): 15.
    [27]
    《煤化工》编辑部. 首套千吨级太阳能发电、电解水制氢、二氧化碳与氢气合成甲醇示范项目试车成功 [J]. 煤化工, 2020, 48(1): 60.

    Editorial Board of Coal Chemical Industry. The first demonstration project of 1,000-ton solar power generation, hydrogen production from electrolyzed water, carbon dioxide and hydrogen for methanol synthesis was successfully commissioned [J]. Coal Chemical Industry, 2020, 48(1): 60.
    [28]
    《石油化工技术与经济》编辑部. 河南顺成与冰岛碳循环签署建CO2制甲醇装置协议 [J]. 石油化工技术与经济, 2019, 35(4): 33.

    Editorial Board of Technology & Economics in Petrochemicals. Henan Shuncheng signed an agreement with Iceland's carbon cycle to build a CO2 methanol plant [J]. Technology & Economics in Petrochemicals, 2019, 35(4): 33.
    [29]
    全国气体标准化技术委员会. 二氧化碳制甲醇技术导则: GB/T 34236—2017 [S]. 北京：中国标准出版社, 2017.

    National Gas Standardization Technical Committee. Technical guideline for methanol preparation from carbon dioxide: GB / T 34236—2017 [S]. Beijing: China Standard Press, 2017.
    [30]
    全国气体标准化技术委员会. 二氧化碳制甲醇安全技术规程: GB/T 34250—2017 [S]. 北京：中国标准出版社, 2017.

    National Gas Standardization Technical Committee. Technical code for safety of methanol preparation from carbon dioxide: GB/T 34250—2017 [S]. Beijing: China Standard Press, 2017.
    [31]
    PREZ-FORTESM, SCHNEBERGERJ C, BOULAMANTIA, et al. Methanol synthesis using captured CO2 as raw material: techno-economic and environmental assessment [J]. Applied Energy, 2016(161):718-732.
    [32]
    WIJKA V, CHATZIMARKAKISJ. Green hydrogen for a European green deal a 2 × 40 GW initatve [R]. Brussels Belgium: Hydrogen Europe, 2020.
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